First Look at Ashley Greene's Sultry DKNY Ad

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Ashley Greene looks stunning in the city, as DKNY's latest muse.  The Twilight star signed on last October as the new face of the brand, following in the footsteps of fashionistas like Alexa Chung and Hilary Duff.

In the campaign, the  striking brunette ditches the pixie-cut her character Alice Cullen sports in all the Twilight films and flaunts her long locks with a sleek, side-parted style, created by celebrity hairstylist Orlando Pita.

Topping off the sophisticated look, is simple yet sexy make-up done by Stephane Marais, featuring bare lips and smoky eyes.

DKNY's Fall 2012 look is inspired by the true city girl: "Someone who has places to go and people to see. Sweet and strong, pretty and tough, smart and street, this season's campaign voyeuristically and strikingly documents a slice of Ashley Greene's life in the city." And shooting her in some of NY's hottest locations, including Tribeca and 5th Avenue, is photographer Peter Lindbergh.

Watch Ashley's DKNY ad below!